Re: Should I get better than 13.5 volts?
Actualy, battery voltage falls as a battery is discharged and it rises as it is recharged. The voltage that the battery can be charged to is determined by the design of the battery but it can never be charged to any more than the maximum of the supply voltage. To fully charge the battery you must have a higher supply voltage than the expected voltage of the battery. The 14.4V will do an excellent job of fully charging the batteries, but if it is maintained at that level for too long, it will begin to boil off the water from the batteries. I don't have any experience with AGM, but it is my understanding that they will be damaged by high voltage above 14V. I suggest that you check that out.
It is normal for the converter of an RV to be set to between 13.5 and 13.7V because that level, while not quite high enough to fully charge a wet cell battery, will get it to about 90% and yet it will not boil most batteries when kept at that voltage for a very long period. AGM batteries are much more voltage sensitive, especially to over voltage. They are longer lived but the also need a lower voltage. I suggest that you talk to the place where you bought the batteries about this. Voltage definately does matter. There are voltage control systems that can be set up for controling solar charging for an AGM battery. I have a lot of experience with batteries and charging in my career, but we never used AGM's so all I really know about them is what I have read. I am a service tech. by trade so have quite a bit of knowledge of flooded cell batteries and power supplies, but very little on solar of AGM.